Influence of water on clumped-isotope bond reordering kinetics in calcite
نویسندگان
چکیده
منابع مشابه
Use of Clumped-isotope Thermometry to Constrain the Crystallization Temperature of Diagenetic Calcite
We describe an approach to estimating the crystallization temperatures of diagenetic calcites using clumped-isotope thermometry, a paleothermometer based on the C–O-bond enrichment in carbonates. Application of this thermometer to calcified gastropod shells and calcite cements in an early Eocene limestone from the Colorado Plateau reveals a record of calcite precipitation and replacement at tem...
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High precision measurements of molecules containing more than one heavy isotope may provide novel constraints on element cycles in nature. These so-called clumped isotope signatures are reported relative to the random (stochastic) distribution of heavy isotopes over all available isotopocules of a molecule, which is the conventional reference. When multiple indistinguishable atoms of the same e...
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[1] The elevation history of Earth’s surface is key to understanding the geodynamic processes responsible for the rise of plateaus. We investigate the timing of Colorado Plateau uplift by estimating depositional temperatures of Tertiary lake sediments that blanket the plateau interior and adjacent lowlands using carbonate clumped isotope paleothermometry (a measure of the temperature‐dependent ...
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The reaction of CO2 hydration/dehydration controls the oxygen isotopic composition in both carbonate minerals and atmospheric CO2 through the exchange of oxygen isotopes with water. The use of O as an environmental indicator typically assumes isotopic equilibrium, namely full oxygen isotope exchange between CO2 and water. Clumped isotopes is a new isotopic tracer that is used in both CaCO3 and ...
متن کاملFriction contribution to water-bond breakage kinetics.
Based on the trajectories of the separation between water molecule pairs from MD simulations, we investigate the bond breakage dynamics in bulk water. From the spectrum of mean first-passage times, the Fokker-Planck equation allows us to derive the diffusivity profile along the separation coordinate and thus to unambiguously disentangle the effects of free-energy and local friction on the separ...
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ژورنال
عنوان ژورنال: Geochimica et Cosmochimica Acta
سال: 2018
ISSN: 0016-7037
DOI: 10.1016/j.gca.2017.12.026